Kinetic and Mechanistic Study of Oxidation of Piperazines by Bromamine-T in Acidic Medium

Kinetic and Mechanistic Study of Oxidation of Piperazines by Bromamine-T in Acidic Medium

Oxidations of piperazine, 1-methylpiperazine and 1-ethylpiperazine by bromamine-T (BAT) in buffered acidic medium have been kinetically studied at 303 K. The reaction shows a first-order dependence of the rate each on [BAT]0 and [piperazine]0, and an inverse fractional-order dependence on [H]. The additions of halide ions and the reduction product of BAT, p-toluenesulfonamide, have no effect on...

Oxidation of Piperazines by Bromamine-B in Acidic Buffer Medium: A Kinetic and Mechanistic Study. Chandrashekar1, BM Venkatesha1*, S Ananda2, and Netkal

1Department of Chemistry, Yuvaraja’s College, University of Mysore, Mysore 57 0005, Karnataka, India. 2Department of Studies in Chemistry, Manasagangothri, University of Mysore, Mysore 57 0006, Karnataka, India. 3Department of Chemistry, Western Illinois University, One University Circle, Macomb, IL 61455, USA. 4Pooja Bhagavat Memorial Mahajana PG Centre, University of Mysore, Mysore, Karnataka...

KINETICS OF OXIDATION OF AMITRIPTYLINE BY BROMAMINE-B AND BROMAMINE-T IN ACIDIC BUFFER (pH 1.2) MEDIUM

study of cohesive devices in the textbook of english for the students of apsychology by rastegarpour

this study investigates the cohesive devices used in the textbook of english for the students of psychology. the research questions and hypotheses in the present study are based on what frequency and distribution of grammatical and lexical cohesive devices are. then, to answer the questions all grammatical and lexical cohesive devices in reading comprehension passages from 6 units of 21units th...

Oxidation of levofloxacin by acidic permanganate: a kinetic and mechanistic study

The kinetic and mechanistic investigation of oxidation of levofloxacin (LF) has been studied by permanganate ion in aqueous sulphuric acid medium at 25°C. The reaction followed first-order kinetics with respect to [LF], and [H+] in their lower concentrations range, tending to zero-order at their higher concentrations. The effect of added products and dielectric constant of the medium was studie...